1H, 13C and 17O NMR spectroscopic study of four bicyclo [3.1.1]heptenes (derivatives of α‐pinene) and four bicyclo[3.1.1]heptanes (derivatives of β‐pinene)
@article{Laihia19921H1A, title={1H, 13C and 17O NMR spectroscopic study of four bicyclo [3.1.1]heptenes (derivatives of α‐pinene) and four bicyclo[3.1.1]heptanes (derivatives of β‐pinene)}, author={K. Laihia and E. Kolehmainen and P. Malkavaara and J. Korvola and P. M{\"a}ntt{\"a}ri and R. Kauppinen}, journal={Magnetic Resonance in Chemistry}, year={1992}, volume={30} }
Four derivatives of 2, 6, 6‐trimethylbicyclo[3.1.1]hept‐2‐ene (α‐pinene) and four derivatives of 2‐methylene‐6, 6‐dimethylbicyclo[3.1.1]heptane (β‐pinene) were synthesized and their 1H, 13C and 17O NMR spectra were measured, analysed and assigned. The 1H NMR spectral parameters were obtained by computer‐aided analyses of the very complex multi‐spin, second‐order spectra. Some of the 13C NMR chemical shift assignments of these compounds reported in the literature should be changed, based on… Expand
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