1D and 3D Polymeric Manganese(II) Thiolato Complexes: Synthesis, Structure, and Properties of    ∞3[Mn4(SPh)8] and ∞1[Mn(SMes)2].


Reactions of [Mn{N(SiMe3)2}2]2 with 2.1 equiv of RSH, R = Ph or Mes = C6H2-2,4,6-(CH3)3, yield compounds of the formal composition "Mn(SR)2". Single-crystal X-ray diffraction reveals that ∞1[Mn(SMes)2] forms one-dimensional chains in the crystal via μ2-SMes bridges, whereas ∞3[Mn4(SPh)8] comprises a three-dimensional network in which adamantanoid cages… (More)
DOI: 10.1021/acs.inorgchem.7b02411


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