10-Silacorroles Exhibiting Near-Infrared Absorption and Emission.

Abstract

10-Silacorroles were obtained from the Pd-catalyzed silylative cyclization of a bis(α,α'-dibromodipyrrin) NiII precursor with dihydrosilanes. These 10-silacorroles show substantially red-shifted absorption bands relative to those of normal porphyrins and isocorroles. Notably, the corresponding free base and ZnII  10-silacorroles exhibit emissions in the NIR… (More)
DOI: 10.1002/chem.201701474

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Cite this paper

@article{Omori201710SilacorrolesEN, title={10-Silacorroles Exhibiting Near-Infrared Absorption and Emission.}, author={Hiroto Omori and Satoru Hiroto and Hiroshi Shinokubo}, journal={Chemistry}, year={2017}, volume={23 33}, pages={7866-7870} }