1,5-Naphthyl-linked bis(imino)pyridines as binucleating scaffolds for dicobalt ethylene oligo-/polymerization catalysts: exploring temperature and steric effects.

@article{Chen201915NaphthyllinkedBA,
  title={1,5-Naphthyl-linked bis(imino)pyridines as binucleating scaffolds for dicobalt ethylene oligo-/polymerization catalysts: exploring temperature and steric effects.},
  author={Q. Chen and Hongyi Suo and Wenjuan Zhang and Randi Zhang and G. A. Solan and Tongling Liang and Wen-Hua Sun},
  journal={Dalton transactions},
  year={2019},
  volume={48 23},
  pages={
          8264-8278
        }
}
Six examples of dinuclear bis(imino)pyridine-cobalt(ii) complexes, [1,5-{2-(CMe[double bond, length as m-dash]N)-6-(CMe[double bond, length as m-dash]N(2,6-R12-4-R2-C6H2))C5H3N}2(C10H6)]Co2Cl4 (R1 = Me, R2 = H Co1; R1 = Et, R2 = H Co2; R1 = iPr, R2 = H Co3; R1 = Me, R2 = Me Co4; R1 = Et, R2 = Me Co5; R1 = CHPh2, R2 = Me Co6), have been prepared from the corresponding bis(tridentate) compartmental ligands (L1-L6) in reasonable yields. The molecular structures of Co3 and Co5 revealed two N,N,N… Expand
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