1,4-Alkyl migration associated with simultaneous S-C bond cleavage and N-C bond formation in platinum complexes of 2-aminothioethers. Characterization of intramolecular interligand charge transfer phenomenon.


Chemical reactions of Pt(pap)Cl(2) [pap = 2-(phenylazo)pyridine] with the N,S-donor atom ligands, 2-alkylthioanilines (HL, (H(2)N--SR), where R = Me, -CH(2)Ph, -CH(2)-CH=CH(2)) in acetonitrile solvent under alkaline conditions yielded mixed chelate donor-acceptor complexes, [Pt(pap)(HN--SR)](+) (1(+), R = Me), [Pt(pap)(HN--S)] (2, HN--S = 2… (More)
DOI: 10.1039/b918336a