σ-Bond electron delocalization of branched oligogermanes and germanium containing oligosilanes

Abstract

In order to evaluate the influence of germanium atoms in oligo- and polysilanes, a number of oligosilane compounds were prepared where two or more silicon atoms were replaced by germanium. While it can be expected that the structural features of thus altered molecules do not change much, the more interesting question is, whether this modification would have… (More)

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