η3-allyl-monocyano-tricarbonylmetallate und η3-allyl-monoisonitril-tricarbonyle des mangans und rheniums

@article{Moll19833allylmonocyanotricarbonylmetallateU,
  title={$\eta$3-allyl-monocyano-tricarbonylmetallate und $\eta$3-allyl-monoisonitril-tricarbonyle des mangans und rheniums},
  author={Matthias Moll and H. Behrens and Hans-J{\"u}rgen Seibold and Peter Merbach},
  journal={Journal of Organometallic Chemistry},
  year={1983},
  volume={248},
  pages={329-341}
}
Abstract The reactions of η3-C3H4RM(CO)4 (η3-C3H5 = allyl for R = H; η3-C4H7 = 2-methylallyl for R = Me; M = Mn, Re) with NaN(SiMe3)2 lead to the formation of the η3-allylmonocyanotricarbonyl metalates [η3-C3H4RM(CO)3CN]− which can be converted into the corresponding isonitrile derivatives η3-C3H4RM(CO)3CNMe or η3-C3H4RM(CO)3CNSnMe3 by treatment with [Me3O]BF4, MeI or Me3SnCl. The new complexes are characterized by their IR and 1H NMR spectra, and in the case of the isonitrile compounds also by… Expand
9 Citations
Selective protonation of terminally bound η3-allyls on (η3-allyl)2(μ2-η3-allyl)2dimolybdenum(II) by β-diketones forming(μ2-η3a-allyl)2(η2-β-diketonate)2 dimolybdenum(II) complexes
Abstract The β-diketones, R(CO)CH2(CO)R′ [where R = R′= Me (acac); R = Me, R′= CF3 (tfac); or R = R′ = CF3 (hfac)] selectively protonate the terminally bound η3-allyls onExpand
13C-NMR-spektren von η3-allyl-komplexen des mangans und rheniums
Abstract The 13 C NMR spectra of η 3 -C 3 H 4 RM(CO) 3 L (C 3 H 5 = allyl for R = H; C 4 H 7 = methylallyl for R = Me; M = Mn, Re; L = CO, CN − , CNMe, CNSnMe 3 ) indicate a trigonal bipyramidalExpand
Metallorganische Lewis‐Säuren, XLVIII. Neue Vorläufer metallorganischer, kationischer Lewis‐Säuren mit zwei freien Koordinationsstellen: (OC)4Re(OEt2)FBF3 und (OC)2(PPh3)2Ru(FBF3)2
Organometallic Lewis Acids, XLVIII[1]. – New Precursors to Organometallic Cationic Lewis Acids with two Accessible Coordination Sites: (OC)4Re(OEt2)FBF3 and (OC)2 (PPh3)2Ru(FBF3)2 The allylExpand
Die kristallstruktur des η3-C3H5Mn(CO)3CNMe (C3H5 = allyl)
Abstract The X-ray structure analysis of the monoclinic η3-C3H5Mn(CO)3CNMe (space group Pa) yields a trigonal-bipyramidal coordination of the manganese atom, in which the isonitrile ligand CNMe andExpand
The Curious Case of the Allyl Ligand: A Study in Applying the 18-Electron Rule
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References

SHOWING 1-5 OF 5 REFERENCES
η1-Allyrhenium pentacarbonyl and η3-allylrhenium tetracarbonyl; preparations, 1H N.M.R., mass and vibrational spectra
Abstract η 1 -C 3 H 5 )Re(CO) 5 has been prepared from [Re(CO) 5 ] − and photo-decarbonylated to give η 3 -C 3 H 5 )Re(Co) 4 . Both allyl complexes have been characterised by 1 H n.m.r., massExpand
13C-NMR-spektren von η3-allyl-komplexen des mangans und rheniums
Abstract The 13 C NMR spectra of η 3 -C 3 H 4 RM(CO) 3 L (C 3 H 5 = allyl for R = H; C 4 H 7 = methylallyl for R = Me; M = Mn, Re; L = CO, CN − , CNMe, CNSnMe 3 ) indicate a trigonal bipyramidalExpand
Die kristallstruktur des η3-C3H5Mn(CO)3CNMe (C3H5 = allyl)
Abstract The X-ray structure analysis of the monoclinic η3-C3H5Mn(CO)3CNMe (space group Pa) yields a trigonal-bipyramidal coordination of the manganese atom, in which the isonitrile ligand CNMe andExpand
13C NMR spectra of η3 -allylmanganesetetracarbonyl compounds; structural implications
The 13C NMR spectra of η3-allylmanganese tetracarbonyl complexes are consistent with an overall Cs, symmetry and involving a σv plane in the Mn(CO)4 fragment. A dynamic carbonyl interchange processExpand