α-Sulfonyl succinimides: versatile sulfinate donors in Fe-catalyzed, salt-free, neutral allylic substitution.

@article{Jegelka2011SulfonylSV,
  title={α-Sulfonyl succinimides: versatile sulfinate donors in Fe-catalyzed, salt-free, neutral allylic substitution.},
  author={Markus Jegelka and B. Plietker},
  journal={Chemistry},
  year={2011},
  volume={17 37},
  pages={
          10417-30
        }
}
Allyl sulfones are versatile intermediates in organic chemistry. The presence of two distinct functional groups sets the stage for a plethora of subsequent transformations. However, despite these advantages the preparation of regioisomerically enriched sulfones is not easy. The use of sulfinate salts as nucleophiles in substitutions is frequently accompanied by side reactions such as π-bond migration, β-elimination, and so on. Herein we present a preparatively simple way to synthesize a variety… Expand
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