{6,6′-Dimeth­oxy-2,2′-[(cyclo­hexane-1,2-di­yl)bis­(nitriliomethyl­idyne)]diphenolato}trinitratolanthanum(III) methanol monosolvate

@inproceedings{Chen201066Dimethoxy22cyclohexane12diylbisnitr,
  title={\{6,6′-Dimeth­oxy-2,2′-[(cyclo­hexane-1,2-di­yl)bis­(nitriliomethyl­idyne)]diphenolato\}trinitratolanthanum(III) methanol monosolvate},
  author={Peng Chen and Yan Bao and Peng-Fei Yan and Guang-Ming Li},
  booktitle={Acta crystallographica. Section E, Structure reports online},
  year={2010}
}
In the title mononuclear complex, [La(NO(3))(3)(C(22)H(26)N(2)O(4))]·CH(3)OH, the La(III) ion is coordinated by three bidentate nitrate counter-ions and one zwitterionic 6,6'-dimeth-oxy-2,2'-[(cyclo-hexane-1,2- di-yl)bis-(nitriliomethyl-idyne)]diphenolate ligand through two phenolate and two meth-oxy O atoms, while the protonated N atoms remain uncoordinated. H atoms located on the two N atoms are involved in intra-molecular hydrogen bonds with the deprotonated phenol O atoms, indicating that… CONTINUE READING

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