{μ-1,2-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]-1,2-diethyl­hydrazine-κ2 P:P′}bis­[chloridogold(I)] tetra­hydro­furan disolvate

@inproceedings{Kriel201112Bisbis4methoxyphenylphosphanyl12di,
  title={\{μ-1,2-Bis[bis­(4-meth­oxy­phen­yl)phosphan­yl]-1,2-diethyl­hydrazine-κ2
               P:P′\}bis­[chloridogold(I)] tetra­hydro­furan disolvate},
  author={Frederik H. Kriel and Manuel A. Fernandes and Judy Coates},
  booktitle={Acta crystallographica. Section E, Structure reports online},
  year={2011}
}
The title compound, [Au(2)Cl(2)(C(32)H(38)N(2)O(4)P(2))]·2C(4)H(8)O, is formed from a bidentate phosphine ligand complexed to two linear gold(I) nuclei [P-Au-Cl = 175.98 (3)°]. The nuclei are 3.1414 (2) Å apart. The mol-ecule exhibits a twofold symmetry axis. Stacks of the compound are formed through inter-molecular C-H⋯Cl inter-actions, while the tetra-hydro-furan (THF) solvate is further attached to the stacks through weak C-H⋯O hydrogen bonding from the THF O atom to two separate H atoms on… CONTINUE READING

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