[UO2 Cl2 (phen)2 ], a Simple Uranium(VI) Compound with a Significantly Bent Uranyl Unit (phen=1,10-phenanthroline).

Abstract

A simple synthesis based on UO2 Cl2 ⋅n H2 O and 1,10-phenanthroline (phen) resulted in the formation of a new uranyl(VI) complex [UO2 Cl2 (phen)2 ] (1), revealing a unique dodecadeltahedron coordination geometry around the uranium center with significant bending of the robust linear arrangement of the uranyl (O-U-O) unit. Quantum chemical calculations on… (More)
DOI: 10.1002/chem.201703009

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