[Glycosides of hydroxylamine derivatives. I. phase transfer synthesis and study of isatine-3-oximes glucosaminides influence on bacterial luminescence].

@article{Kurianov2011GlycosidesOH,
  title={[Glycosides of hydroxylamine derivatives. I. phase transfer synthesis and study of isatine-3-oximes glucosaminides influence on bacterial luminescence].},
  author={V O Kur'ianov and T. A. Chupakhina and Anna A Shapovalova and Andrey M. Katsev and V. I. Chirva},
  journal={Bioorganicheskaia khimiia},
  year={2011},
  volume={37 2},
  pages={
          259-68
        }
}
In the phase transfer system solid calcium carbonate-acetonitrile, per acetate alpha-D-glucosaminilchloride glycosilate easily deprotoned isatine-3-oximes hydroxyl groups. It was found that the presence in the reaction mixture a catalytic amounts of 15-crown-5 accelerated the process twice. Obtained O-beta-D-glucosaminides were identified with 1H-NMR spectroscopy. Features of synthesized compound's NMR spectra are discussed in comparison with those of another N-acetylglucosamine 1-O-derivatives… CONTINUE READING

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