[Disulfanediylbis(ferrocenyl­thio­phosphinato)-κ2 O,O]titanocene tetra­hydro­furan tris­olvate


The title compound, [Fe(2)Ti(C(5)H(5))(4))(C(10)H(8)O(2)P(2)S(4))]·3C(4)H(8)O, contains a central seven-membered TiO(2)P(2)S(2) ring with a very similar geometry compared to the derivative showing anisyl instead of ferrocenyl substituents, the Ti-O distance being marginally longer for the anisyl derivative. Two tetra-hydro-furan solvent mol-ecules are each… (More)
DOI: 10.1107/S1600536812010811


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@inproceedings{Karaku2012Disulfanediylbisferrocenylthiophosp, title={[Disulfanediylbis(ferrocenyl­thio­phosphinato)-κ2 O,O]titanocene tetra­hydro­furan tris­olvate}, author={Mehmet Karakuş and J Derek Woollins and Peter L{\"o}nnecke and Evamarie Hey-Hawkins}, booktitle={Acta crystallographica. Section E, Structure reports online}, year={2012} }