[Development of new synthetic method and function of ynolate anions].

  • Miki Shindo
  • Published 2000 in
    Yakugaku zasshi : Journal of the Pharmaceutical…

Abstract

Ynolates are carbanions having a triple bond in place of the double bond in enolate anions. Ynolates are ketene anion equivalents, thus ynolates introduce a ketene unit into substrates and the resulting products possess high reactivity. This allows ynolates to undergo unique reaction sequences. For the past 20 years, several methods for the generation of… (More)

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