[Cs6 Cl][Fe24 Se26 ]: A Host-Guest Compound with Unique Fe-Se Topology.


The novel host-guest compound [Cs6Cl][Fe24Se26] (I4/mmm; a=11.0991(9), c=22.143(2) Å) was obtained by reacting Cs2Se,CsCl, Fe, and Se in closed ampoules. This is the first member of a family of compounds with unique Fe-Se topology, which consists of edge-sharing, extended fused cubane [Fe8Se6Se8/3] blocks that host a guest complex ion, [Cs6Cl](5+). Thus Fe… (More)
DOI: 10.1002/chem.201504840


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