[Co(bpy)3](3+/2+) and [Co(phen)3](3+/2+) electron mediators for overall water splitting under sunlight irradiation using Z-scheme photocatalyst system.


[Co(bpy)3](3+/2+) and [Co(phen)3](3+/2+) redox couples were revealed to play as electron mediators for Z-scheme photocatalyst systems composed of Ru/SrTiO3:Rh and BiVO4 powders for overall water splitting under visible light irradiation. These electron mediators were effective for only the combination of SrTiO3:Rh with BiVO4. They did not work when nondoped… (More)
DOI: 10.1021/ja400238r


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