[Cd3(H2O)3((O3PCH2)2NH-CH2C6H4-COOH)2].11H2O: a layered cadmium phosphonate with reversible dehydration/hydration properties.

@article{Bauer2007Cd3H2O3O3PCH22NHCH2C6H4COOH211H2OAL,
  title={[Cd3(H2O)3((O3PCH2)2NH-CH2C6H4-COOH)2].11H2O: a layered cadmium phosphonate with reversible dehydration/hydration properties.},
  author={Sebastian Bauer and J{\'e}r{\^o}me Marrot and Thomas Devic and G{\'e}rard F{\'e}rey and Norbert Stock},
  journal={Inorganic chemistry},
  year={2007},
  volume={46 23},
  pages={9998-10002}
}
In a recent systematic study on the influence of the reaction temperature on the structure formation in the system CdCl2/H(HO3PCH2)2NH-CH2C6H4-COOH (H5L) /NaOH, [Cd3(H2O)3((O3PCH2)2NH-CH2C6H4-COOH)2].11H2O was obtained as a microcrystalline compound. We have now been able to elucidate the structure from single-crystal data: triclinic, P; a=5.4503(9), b=12.880(2), and c=16.417(3) A; alpha=67.841(6) degrees, beta=80.633(6) degrees, gamma=87.688(8) degrees, V=1052.9(3) A3; Z=1; R1=0.1143, R2=0… CONTINUE READING

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