[2-(1-{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN 1}eth­yl)phenolato-κO](pyridine-κN)nickel(II)


The Ni(II) atom in the title complex, [Ni(C₁₁H₁₃N₃OS)(C₅H₅N)], exists within a square-planar N₃O donor set provided by N,N',O atoms of the dianionic tridentate ligand and a pyridine N atom. The maximum deviation from the ideal geometry is seen in the N-Ni-N five-membered chelate bite angle of 83.28 (12)°. The pyridine mol-ecule forms a dihedral angle of 44… (More)
DOI: 10.1107/S1600536812026177


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@inproceedings{Takjoo2012212Azanidylethylsulfanylmethylidene, title={[2-(1-\{2-[Aza­nid­yl(ethyl­sulfan­yl)methyl­idene-κN]hydrazin-1-yl­idene-κN 1\}eth­yl)phenolato-κO](pyridine-κN)nickel(II)}, author={Reza Takjoo and S. Ng and Edward R. T. Tiekink}, booktitle={Acta crystallographica. Section E, Structure reports online}, year={2012} }