[1,2-Bis(diphenyl­phosphan­yl)ethane-κ2 P,P′]{2-[(4-nitro­benzoyl­meth­yl)diphenyl­phosphan­yl]phenyl-κ2 C,C′}palladium(II) trifluoro­methane­sulfonate–dichloro­methane–n-hexane (1/1/0.5)

@inproceedings{Rizzoli201112Bisdiphenylphosphanylethane2,
  title={[1,2-Bis(diphenyl­phosphan­yl)ethane-κ2
               P,P′]\{2-[(4-nitro­benzoyl­meth­yl)diphenyl­phosphan­yl]phenyl-κ2
               C,C′\}palladium(II) trifluoro­methane­sulfonate–dichloro­methane–n-hexane (1/1/0.5)},
  author={Corrado Rizzoli and Kazem Karami and Farzaneh Borzooie},
  booktitle={Acta crystallographica. Section E, Structure reports online},
  year={2011}
}
In the cation of the title compound, [Pd(C(26)H(19)NO(3)P)(C(26)H(24)P(2))]CF(3)O(3)S·CH(2)Cl(2)·0.5C(6)H(14), the Pd(II) atom has a slightly tetra-hedrally distorted square-planar coordination geometry. The PdC(3)P and PdC(2)P(2) five-membered metallacycles adopt envelope and twist conformations, respectively. In the crystal, inter-molecular C-H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dichloro-methane solvent mol-ecule is disordered over three… CONTINUE READING