(Oligo)aromatic species with one or two conjugated Si[double bond, length as m-dash]Si bonds: near-IR emission of anthracenyl-bridged tetrasiladiene.

@article{Obeid2017OligoaromaticSW,
  title={(Oligo)aromatic species with one or two conjugated Si[double bond, length as m-dash]Si bonds: near-IR emission of anthracenyl-bridged tetrasiladiene.},
  author={Naim M Obeid and Lukas Klemmer and Daniel Maus and Michael Patrick Zimmer and Jonathan Jeck and Iulia Bejan and Andrew J P White and Volker Huch and Gregor Jung and David Scheschkewitz},
  journal={Dalton transactions},
  year={2017},
  volume={46 27},
  pages={8839-8848}
}
A series of aryl disilenes Tip2Si[double bond, length as m-dash]Si(Tip)Ar (2a-c) and para-arylene bridged tetrasiladienes, Tip2Si[double bond, length as m-dash]Si(Tip)-LU-Si(Tip)[double bond, length as m-dash]SiTip2 (3a-d) are synthesized by the transfer of the Tip2Si[double bond, length as m-dash]SiTip unit to aryl halides and dihalides by nucleophilic disilenides Tip2Si[double bond, length as m-dash]SiTipLi (Tip = 2,4,6-iPr3C6H2, Ar = aryl substituent, LU = para-arylene linking unit). The… CONTINUE READING
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