(Acetonitrile-N)(o-benzoquinone diimine-N,N')chloro-trans-bis(triphenylphosphine-P)ruthenium(II) hexafluorophosphate 0.25-hydrate.

Abstract

The Ru atom in the title compound, [RuCl(CH(3)CN){P(C(6)H(5))(3)}(2){C(6)H(4)(NH)(2)}]PF(6).0.25H(2)O, has a six-coordinate octahedral geometry, with a trans arrangement of the triphenylphosphine groups. The asymmetric unit contains two complex molecules and a partially occupied water site. Principal dimensions include Ru-N 1.958 (4)-2.044 (5), Ru-P 2.3897… (More)

Topics

  • Presentations referencing similar topics