(6R,10S)-Pallantione: the first ketone identified as sex pheromone in stink bugs.

@article{Fvaro20136R10SPallantioneTF,
  title={(6R,10S)-Pallantione: the first ketone identified as sex pheromone in stink bugs.},
  author={Carla F. F{\'a}varo and Rafael A. Soldi and Tetsu Ando and Jeffrey Richard Aldrich and Paulo H. G. Zarbin},
  journal={Organic letters},
  year={2013},
  volume={15 8},
  pages={1822-5}
}
This work describes the structural elucidation of the sex pheromone of the soybean stink bug, Pallantia macunaima. The biological activity of the synthetic pheromone was demonstrated by behavioral and EAD experiments. Furthermore, the absolute configuration of the natural pheromone was determined as (6R,10S)-6,10,13-trimethyltetradecan-2-one. This is the first ketone identified as a male-produced sex pheromone in Pentatomidae, and the trivial name, pallantione, was assigned to this novel… CONTINUE READING
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