(2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ3 N,N′,O 6)(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ3 N,N′,O 6)rhodium(III)

@inproceedings{Wang201222Bipyridine66dicarboxylato3N6,
  title={(2,2′-Bipyridine-6,6′-dicarboxyl­ato-κ3
N,N′,O
6)(6′-carb­oxy-2,2′-bipyridine-6-carboxyl­ato-κ3
N,N′,O
6)rhodium(III)},
  author={Huimin Wang and Xiaojun Gu and Bingbing Zhang and Haiquan Su and Ming Hu},
  booktitle={Acta crystallographica. Section E, Structure reports online},
  year={2012}
}
The Rh(III) ion in the title compound, [Rh(C(12)H(6)N(2)O(4))(C(12)H(7)N(2)O(4))], is coordinated by four N atoms and two O atoms from two chelating ligands L and HL (H(2)L = 2,2'-bipyridine-6,6'-dicarb-oxy-lic acid) to form a distorted octa-hedral geometry. Face-to-face π-stacking inter-actions are observed between inversion-related pyridine rings, with a… CONTINUE READING