"Zeoball" [Sn36Ge24Se132]24-: a molecular anion with zeolite-related composition and spherical shape.

@article{Lin2012ZeoballA,
  title={"Zeoball" [Sn36Ge24Se132]24-: a molecular anion with zeolite-related composition and spherical shape.},
  author={Yumei Lin and Werner Massa and Stefanie Dehnen},
  journal={Journal of the American Chemical Society},
  year={2012},
  volume={134 10},
  pages={4497-500}
}
Ionothermal reactions of [Ge(4)Se(10)](4-) with SnCl(4)·5H(2)O yielded [BMMIm](24)[Sn(36)Ge(24)Se(132)] (ZBT-1) and [BMIm](24)[Sn(32.5)Ge(27.5)Se(132)] [ZBT-2; B(M)MIm = 1-butyl-(2,)3-(di)methylimidazolium]. These contain the largest known discrete polyanion consisting only of main-group elements. In spite of a zeolite-related composition, the 192-atom "zeoball" anion adopts a spherical shape, which has been unprecedented in the chemistry of zeolites and their homologues and relatives… CONTINUE READING
Related Discussions
This paper has been referenced on Twitter 1 time. VIEW TWEETS

From This Paper

Figures, tables, and topics from this paper.

Explore Further: Topics Discussed in This Paper

Citations

Publications citing this paper.

References

Publications referenced by this paper.
Showing 1-3 of 3 references

Nierengarten, J.-F.; Eds.; Royal Society of Chemistry

F. Langa De La Puente
J. Am. Chem. Soc. • 2011

2604 and references therein

P. N. Trikalitis, K. K. Rangan, M.G.J. Am. Kanatzidis
In Fullerenes: Principles • 2002

Energy Mater. Sol

Z. Kebede, S.-E. Sol. Lindquist
Cells • 1999

Similar Papers

Loading similar papers…