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Comparative Study on Temperature-Dependent CO2 Sorption Behaviors of Two Isostructural N-Oxide-Functionalized 3D Dynamic Microporous MOFs.
TLDR
Two isostructural 3D dynamic porous Cu(II) metal-organic frameworks (MOFs) have been synthesized, which have high CO2 uptake, CO2 sorption affinity, and sorption selectivities of CO2 over CH4 and N2. Expand
Conversion of two stereocenters to one or two chiral axes: atroposelective synthesis of 2,3-diarylbenzoindoles† †Electronic supplementary information (ESI) available. CCDC 1884267, 1891943, 1882145,
Central-to-axial chirality conversion provides efficient access to axially chiral compounds, and several examples regarding the conversion of one, two or four stereocenters to one axis have beenExpand
Enantioselective Total Synthesis of Pseudopteroxazole and Ileabethoxazole.
TLDR
Cationic cyclizations of 13 and 24 demonstrated an effective pathway for the construction of the opposite configurations at C1 in 1 and 2 and an approach for the introduction of methyl at C4 is a feasible solution for structural modifications at C3 of 1 and2. Expand
Selectfluor-Mediated Stereoselective [1 + 1 + 4 + 4] Dimerization of Styrylnaphthols.
TLDR
DFT calculations indicate that this method merges an intriguing stereoselective intermolecular 1 + 1 radical coupling to construct a bridged C-C bond and then an intramolecular [4 + 4] formal cycloaddition of the in situ generated o-quinone methide intermediate. Expand
In Vitro and In Silico Antioxidant Activity of Novel Peptides Prepared from Paeonia Ostii ‘Feng Dan’ Hydrolysate
TLDR
Five novel antioxidant peptides were prepared from Paeonia ostii seed meal and demonstrated no obvious cytotoxicity to L929 fibroblast cells, suggesting they might potentially have excellent uses in functional foods, nutraceuticals and pharmacological products. Expand
5‐hydroxymethylfurfural‐ and fluorescein‐fused fluorescence probe of mast cells (RBL‐2H3): Synthesis, photophysical properties, and bioimaging
TLDR
Compared with other fluorescein derivatives, Fluo‐HMF could specially label RBL‐2H3 cells and could be used as a fluorescent probe for bioimaging on some related research of allergic mechanism. Expand