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Copper-catalysed N-arylation of Pyrrole with Aryl Iodides Under Ligand-free Conditions
A simple, inexpensive and ligand-free copper-catalysed N-arylation of pyrrole with aryl iodides has been developed giving N-arylated products in moderate to excellent yields. The catalyst loading is
Antiferromagnetic Copper(II) Metal–Organic Framework Based Quartz Crystal Microbalance Sensor for Humidity
A novel copper metal–organic framework (MOF) [Cu3L2(H2O)2.75]·0.75H2O·1.75DMA (H3L = 4-(2-carboxyphenoxy)-isophthalic acid, DMA = dimethylacetamide) has been synthesized and structurally
Two 1D homochiral heterometallic chains: crystal structures, spectra, ferroelectricity and ferromagnetic properties
Two new homo chiral Cu–Ln (Ln = Gd and Ho) compounds bearing a chiral Schiff base ligand (1R,3S)-N′,N′′-bis[3-methoxysalicylidene]-1,3-diamino-1,2,2-trimethylcyclopentane (H2L) have been synthesized
Characteristic Components and Authenticity Evaluation of Rape, Acacia, and Linden Honey.
The results reveal that 10% of commercial honeys were pure syrups, which seems to propose a novel and reliable solution to assess the authenticity of monofloral honey.
Mechanism of protective effect of carnosol on pig intestinal epithelial cells.
Carnosol has a protective effect on intestinal epithelial cells by up-regulating the expression of Nrf2 and inhibiting p21 protein to promote the expression in CCND1 and SOD genes.
Controllable Fabrication of One-Dimensional and Two-Dimensional Compounds with Heterometallic Units: Syntheses, Crystal Structures, and Magnetic Properties
A heterometallic Cu-Ln dinuclear compound [(Me2CO)Cu(L)Dy(NO3)3] (1) (L = chiral Schiff base ligand) has been synthesized and structurally characterized. Employing the dinuclear compounds as second...