Zhoutong He

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The effect of pressure on the deposition of nanocrystalline diamond (NCD) Films in a hot filament chemical vapor deposition (IFCVD) system was investigated using CH<sub>4</sub>/H<sub>2</sub>/Ar gas mixture. The reactor pressure was found to have the strongest influence on nucleation of nanocrystalline diamond films. The range of Ar concentration in the(More)
A novel enneanuclear manganese complex, [Mn(9)O(4)(Mesao)(6)(MeO)(3)(O(2)CMe)(3)(OH)(MeOH)(2)]·2.5DMF [1; Me-saoH(2) = 2-hydroxyphenylethanone oxime], was synthesized. The structure of 1 contains an unusual [Mn(9)O(4)] core with an unprecedented defective "supertetrahedron" topology based on two parallel, onset stacked 9-MC-3 and 15-MC-6 metallacrown(More)
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