Zhen Lu Shen

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The room temperature ionic liquid [bmim][PF 6 ] was employed as the reaction medium in the asymmetric glyoxylate-ene reaction of α-methyl styrene (4a) with ethyl glyoxylate using chiral palladium(II) complexes as the catalysts. [Pd(S-BINAP)(3,5-CF 3-PhCN) 2 ](SbF 6) 2 (1b) showed the highest catalytic activity. Under the reaction conditions of 40 o C, 0.5(More)
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