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A mononuclear dysprosium complex featuring single-molecule-magnet behavior.
TLDR
The Dy ion, which possesses a Kramers ground state of H15/2, is an appealing paramagnetic source for the construction of SMMs in a suitable ligand-field symmetry and strength, and all three reported types of single-ion magnets are found with a high-order single axis defining the local symmetry. Expand
Detection of huntingtin exon 1 phosphorylation by Phos-Tag SDS-PAGE: Predominant phosphorylation on threonine 3 and regulation by IKKβ.
TLDR
Using a modified SDS-PAGE protocol (Phos-Tag) followed by Western blotting with specific anti-HUNTINGTIN antibodies, huntingtin fragments expressed in cellular contexts based on the presence of phosphorylated residues are efficiently resolved and threonine 3 is defined as the major site of huntingtin N17 phosphorylation. Expand
Spin crossover in a series of iron(II) complexes of 2-(2-Alkyl-2H-tetrazol-5-yl)-1,10-phenanthroline: effects of alkyl side chain, solvent, and anion.
TLDR
It is proved that the alkyl side chains play a crucial role in the complicated SCO behaviors in this system, corresponding to sequential phase transitions from the low-spin (LS) phase to the intermediate phase and then to the high-spin phase, respectively, proved by crystal structure analysis and 57Fe Mössbauer spectroscopy. Expand
An organometallic single-ion magnet.
TLDR
An organometallic single-ion magnet is synthesized with only 19 non-hydrogen atoms featuring an erbium ion sandwiched by two different aromatic ligands and shows a butterfly-shaped hysteresis loop at 1.8 K. Expand
Strategies towards single-chain magnets
Abstract Single-chain magnets (SCM) are a novel class of molecular magnetic materials exhibiting slow magnetic relaxation, which arises from large uniaxial type magnetic anisotropy, strong intrachainExpand
An azido-bridged disc-like heptanuclear cobalt(II) cluster: towards a single-molecule magnet.
TLDR
A disc-like heptanuclear Co(II)-cluster, [Co7( bzp)6(N3)9(CH3O)3].2ClO4.2H2O (1) (bzp = 2-benzoyl pyridine) shows slow relaxation at static zero and non-zero fields below 6 K, towards single molecule magnet behavior. Expand
Coordination polymers with end-on azido and pyridine carboxylate N-oxide bridges displaying long-range magnetic ordering with low dimensional character.
A series of 2D and one 3D transition-metal-azido coordination polymers with pyridine carboxylate N-oxide, isonicotinate N-oxide (INO), and nicotinate N-oxide (NNO) as the coligands were synthesizedExpand
Phase transitions, prominent dielectric anomalies, and negative thermal expansion in three high thermally stable ammonium magnesium-formate frameworks.
TLDR
Three Mg-formate frameworks, incorporating three different ammoniums, display structural phase transitions accompanied by prominent dielectric anomalies and anisotropic and negative thermal expansion, and the materials are all found to be thermally stable up to 470 K. Expand
Kirenol exerts a potent anti-arthritic effect in collagen-induced arthritis by modifying the T cells balance.
TLDR
Kirenol is evaluated as a potential immunosuppressant for the treatment for rheumatoid arthritis and significantly delayed the occurrence and reduced the disease severity of CIA. Expand
[NH2NH3][M(HCOO)3] (M = Mn2+, Zn2+, Co2+ and Mg2+): structural phase transitions, prominent dielectric anomalies and negative thermal expansion, and magnetic ordering
We report here a new class of ammonium metal–formate frameworks of [NH2NH3][M(HCOO)3] (M = Mn2+, Zn2+, Co2+ and Mg2+) incorporating hydrazinium as the cationic template and component. The perovskiteExpand
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