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A cyclometalation reaction involving C-F bond activation at a cobalt(i) center with an aldazine-N atom as anchoring group affords ortho-chelated cobalt(iii) complexes containing a [C-Co-F] fragment [CoFMe(PMe(3))(2){(C(6)H(3)F-ortho)CH[double bond, length as m-dash]N-R}] 5-8. Under similar reaction conditions π-coordinated cobalt(0) complexes(More)
The title compound, [Co(C(30)H(23)O(2)P(2))(C(3)H(9)P)(2)], was synthesized by the addition of a Co(PMe(3))(4) solution to (PPh(2)O)(2)C(6)H(4). The Co(I) atom displays a trigonal-bipyramidal geometry with the two P atoms of the 'PCP' pincer ligand and the P atom of one of the trimethyl phosphine ligands forming the basal plane, whereas the metalated C atom(More)
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