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RANEY® Ni catalyzed transfer hydrogenation of levulinate esters to γ-valerolactone at room temperature.
A catalytic transfer hydrogenation process was developed for the production of γ-valerolactone (GVL) from ethyl levulinate (EL) and a H-donor at room temperature. Ethyl levulinate was almostExpand
High and selective CO2 capture by two mesoporous acylamide-functionalized rht-type metal-organic frameworks.
TLDR
Two mesoporous and flexible acylamide-functionalized rht-type MOFs exhibit not only high excess unsaturation CO(2) uptake at 20 bar and 273 K, but also good selectivity of CO( 2)/CH(4) andCO(2)/N(2), confirmed by GCMC and first-principles calculations. Expand
Asymmetric total synthesis of (-)-lingzhiol via a Rh-catalysed [3+2] cycloaddition.
TLDR
An efficient [3+2] cycloaddition reaction between an enal and an alleno rhodium species, which was generated in situ from the corresponding enynol via a retro metal-propargylation reaction, to give bicyclic systems bearing two quaternary atoms at their bridgehead positions is reported. Expand
Enhancement of skin permeation of bufalin by limonene via reservoir type transdermal patch: formulation design and biopharmaceutical evaluation.
TLDR
Current reservoir transdermal patch containing 10% D-limonene as a permeation enhancer, 40% ethanol, 30% PG and 15% carbopol-water gel complex provided an improved sustained release of bufalin through transder mal administration. Expand
Microbial transformation of 3β-acetoxypregna-5,16-diene-20-one by Penicillium citrinum
TLDR
The 7-O-methylation is a novel reaction in the field of microbial transformation of pregnane steroids that resulted in the production of four metabolites 2-5. Expand
Pathway and kinetics of malachite green biodegradation by Pseudomonas veronii
TLDR
The present study is the first to report the degradation of malachite green by P. veronii and the identification of hydroquinone as a metabolite in the degradation pathway and proposes a possible degradation pathway based on these findings. Expand
Isolation and Asymmetric Total Synthesis of Perforanoid A.
TLDR
Preliminary studies show that perforanoid A is cytotoxic towards HEL, K562, and CB3 tumor cell lines. Expand
Total synthesis of (±) maoecrystal V.
A concise first total synthesis of (±) maoecrystal V (1) is reported. The synthesis features a Wessely oxidative dearomatization of a phenol, an intramolecular Diels-Alder reaction, and aExpand
Highly selective CO2 capture of an agw-type metal-organic framework with inserted amides: experimental and theoretical studies.
An amide-inserted metal-organic framework (NJU-Bai3) presents high storage and high selectivity toward CO(2) and combines these two interesting characters which strongly support our expectation thatExpand
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