Zhao-Jian Hu

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A fluorinated bis(triazole) ligand, 1,4-bis(1,2,4-triazol-1-ylmethyl)-2,3,5,6-tetrafluorobenzene (Fbtz), was applied to coordinate with a series of Mn(II), Co(II), Fe(II), and Cu(II) ions, respectively. In comparison with its nonfluorinated analogue 1,4-bis(1,2,4-triazol-1-ylmethyl)benzene (btx), Fbtz is able to build six novel metal-organic frameworks by(More)
The title compound, C(20)H(18)N(4), is a flexible 3,3'-bipyridyl-type ligand with a long spacer group between the two pyridyl functions. The mol-ecule crystallizes around an inversion center, with one half-mol-ecule in the asymmetric unit and a dihedral angle of 71.85 (8)° between the pyridine ring and the central benzene ring.
In the crystal structure of the title compound, C(12)H(13)N(6) (+)·ClO(4) (-), the cation, located about an inversion center, is monoprotonated, and one H atom is disordered over two sites on N atoms of the two triazole rings, each with an occupancy factor of 0.5. The perchlorate anion has C(2) symmetry, the Cl atom and one O atom lying on the twofold(More)
An ice-like hexameric water cluster, stabilized by the flexible bis-imidazolyl compound 2,3,5,6-tetrafluoro-1,4-bis(imidazol-1-ylmethyl)benzene (Fbix), is found in the trigonal R3 crystal structure of the title compound, C(14)H(10)F(4)N(4).2H(2)O or Fbix.2H(2)O. The Fbix molecule lies about an inversion centre with one water molecule in the asymmetric unit(More)
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