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The first copper-catalyzed reductive aldol addition/lactonization domino reactions of α,β-unsaturated dicarboxylate esters with ketones were achieved in high yields. The method, which involves easily… (More)
Abstract A quantitative structure–property relationship (QSPR) study was performed for the prediction of the natural logarithm of infinite dilution activity coefficients, ln( γ ∞ ), of 45 chlorinated… (More)
Abstract PMMA-coating PNIPAM particles were prepared via a rapid microwave-assisted polymerization. The PMMA shell was found to have a limitation on the movement of PNIPAM chains, which resulted in a… (More)
Copper hydride derived from CuF(PPh3)3·2MeOH-bis[(2-diphenylphosphino)phenyl] ethersilane can reduce electron-deficient olefins selectively and efficiently.
β-Carboalkoxy-γ-lactams were synthesized in high yields via copper-catalyzed three-component reactions of α,β-unsaturated dicarboxylate esters, aldimines, and a silane. The reaction proceeds in a… (More)
A copper-catalyzed cascade reaction of α,β-unsaturated esters with keto esters is reported. It features a copper-catalyzed reductive aldolization followed by a lactonization. This method provides a… (More)
The quantitative structure-property relationship (QSPR) was studied for the prediction of glass transition temperatures of polystyrenes on a set of 107 polystyrenes using artificial neural networks… (More)
The title compounds are prepared with high trans-selectivity from aldimines (I) and (IV) and maleates (II) and (VI) in the presence of polymethylhydrosiloxane (PMHS).