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Journals and Conferences
The hydrosilylation reaction of diphenylsilane and phthalaldehyde is catalyzed by heteroscorpionate zinc hydride complex LZnH (1, L = (Me Pz)2 CP(Ph)2 NPh, Me Pz = 3,5-dimethylpyrazolyl). Both… (More)
A highly isotactic stereoblock PLA has been obtained using the achiral heteroscorpionate zwitterionic zinc complexes as catalysts, for the first time, via a chain-end control mechanism.
The first neutral rare-earth metal dinuclear dihydrido complexes [(NPNPN)LnH2]2 (2-Ln; Ln = Y, Lu; NPNPN: N[Ph2PNC6H3((i)Pr)2]2) bearing μ2-bridging hydride ligands have been synthesized. In the… (More)
A CpPN-based scandium terminal imido complex was isolated, which could induce the intramolecular C-H bond activation of a phenyl group even at room temperature.