Zanele H. Phasha

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In the title mol-ecule, C(10)H(17)PSe, the P atom has a distorted tetra-hedral environment resulting in an effective cone angle of 165°. The benzene ring makes dihedral angles of 70.04 (8) and 77.28 (8)° with the phenyl rings, while the dihedral angle between the phenyl rings is 62.95 (8)°. In the crystal, mol-ecules are linked by C-H⋯π inter-actions.
In the title compound, C14H14O4, the prop-2-yn-yloxy O-C-C C plane [maximum deviation = 0.0116 (12) Å] forms a dihedral angle of 78.44 (9)° with the benzofuran-3(2H)-one ring system. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, forming a tape along the a-axis direction. C-H⋯O inter-actions are observed between the tapes.
In the title compund, C(21)H(33)PSe, the Se=P bond is part of a distorted tetra-hedral environment on the P atom. Both cyclo-hexyl groups adopt chair conformations. A cone angle of 170° was calculated using an adaptation of the Tolman model. Inter-molecular C-H⋯Se and C-H⋯Cg contacts are observed (Cg is the centroid of the benzene ring).
In the title compound, C30H33BrO6, the pyran-ose ring adopts a chair conformation. Two of the O-benzyl phenyl rings lie almost perpendicular to C/C/C/O plane formed by the ring atoms not attached to these O-benzyl phenyl rings, and form dihedral angles of 85.1 (2) and 64.6 (2)°, while the third O-benzyl phenyl ring is twisted so that it makes a dihedral(More)
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