Yumiko Sekiguchi

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The synthesis and structures of new 16-electron disilene palladium complexes with 2,6-dimethylphenyl isocyanide and phenyldimethylphosphine ligands [L(1)L(2)Pd{(t-BuMe(2)Si)(2)Si=Si(SiMe(2)Bu-t)(2)}, where L(1) = L(2) = PhMe(2)P; L(1) = (cyclohexyl)(3)P, L(2) = 2,6-dimethylphenyl isocyanide; L(1) = L(2) = 2,6-dimethylphenyl isocyanide] are described.(More)
The first 14-electron disilene palladium complex eta2-[tetrakis(tert-butyldimethylsilyl)disilene](tricyclohexylphosphine)palladium (4) was synthesized. In the solid state, complex 4 has one tricyclohexylphosphine ligand bound unsymmetrically to the palladium center in regard to the eta2-disilene moiety. The elongation of the Si-Si bond length from that of(More)
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