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[Ir(6)(μ-alloCl(2)(2-))(3)(Cp*)(6)(OH)(3)](PF(6))(3) (1) having 7,8-dichloroalloxazine dianion (alloCl(2)(2-)) as bridging ligands was synthesized and characterized by X-ray crystallography, spectroscopic and electrochemical measurements. The alloxazine ligands showed unprecedented coordination modes to link the six Ir(III) centres. The complex exhibited(More)
A novel tetranuclear Ir(iii) complex involving unprecedented coordination modes of alloxazine formed a closed pi-space by intermolecular hydrogen bonding and the counter anions encapsulated in the space could be exchanged via self-assembly.
The formation of guanine quartets with 9-isopropylguanine ((i)PG) is discussed in organic solvents. Crystal structures of the (i)PG quartets were determined by X-ray crystallography with template cations (Na(+) and Ca(2+)) and the structure without a template cation was also obtained by virtue of the stabilization by intermolecular hydrogen bonding with(More)
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