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Dye-sensitized solar cells (DSSCs) are built from nanocrystalline anatase TiO(2) with a 101 crystal face (nc-TiO(2)) onto which a dye is absorbed, ruthenium complex sensitizers, fluid I(-)/I(3)(-) redox couples with electrolytes, and a Pt-coated counter electrode. DSSCs have now reached efficiencies as high as 11%, and G24 Innovation (Cardiff, U.K.) is(More)
Polyaniline(PANI) microwires containing CdS nanoparticles have been prepared by introducing hydrogen bonding and/or electrostatic interaction between mercaptocarboxylic acid capped CdS nanoparticles and PANI. SEM and TEM proved them to be wire-like structures. PL spectra of the PANI/CdS complex is blue-shifted by 14 nm compared to CdS nanoparticles in(More)
In this paper, a general and efficient strategy has been developed to produce nitrogen-doped graphene sheets (NGs) based on hard and soft acids and bases (HSAB) theory. Under hydrothermal conditions, any salt with amphiprotic character have a strong tendency to hydrolysis, it is possible to provide reducing agent and nitrogen source simultaneously. It is(More)
Colloidal TiO2 anatase nanoparticles of 4-8 nm diameter capped with 3,6,9-trioxadecanoic acid (TODA) were synthesized at low temperature using water and ethanol as the solvents. ATR-FTIR and (1)H NMR characterization showed the capping acid capability of stabilizing the TiO2 nanoparticles through labile hydrogen bonds. The presence of the capping ligand(More)
Z907-sensitized solar cells incorporating a phenyl-capped aniline tetramer (EPAT) as a substitute of the iodine/iodide redox couple in the electrolytes produce an enhanced open-circuit voltage and short circuit photocurrent density when tert-butylpyridine (TBP) is added to the electrolyte.
We have synthesized a series of four new promising D-π-A conjugated organic sensitizers with a proaromatic 4H-pyran-4-ylidene as a donor, a thiophene ring in the bridge, and 2-cyanoacrilic acid as acceptor. Comparison between different donor substituents and the modification of the thiophene ring resulted in molar extinction coefficients as high as 36399(More)
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