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Cyclometalated [Cp*M(C^X)] (M = Ir, Rh; X = N, C, O, P) complexes.
Half-sandwich Cp*Ir and Cp*Rh metalacycles have been successfully applied in traditional domains encompassing organic transformations and catalysis in recent years, especially the catalyticExpand
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Preparation and Post-Assembly Modification of Metallosupramolecular Assemblies from Poly( N-Heterocyclic Carbene) Ligands.
Although the coordination chemistry of N-heterocyclic carbenes (NHCs) with transition metals has been explored for half a century, only in the past ten years has the chemistry ofExpand
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Synthesis and characterization of half-sandwich iridium complexes containing 2,6(7)-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene and ancillary ortho-carborane-1,2-dichalcogenolato ligands
Abstract The binuclear half-sandwich iridium complexes {Cp ∗ IrCl 2 } 2 (μ-2,6(7)-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene) ( 3 ) and {Cp ∗ Ir[E 2 C 2 (B 10 H 10 )]} 2Expand
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Synthesis and structural characterization of binuclear half-sandwich iridium, rhodium and ruthenium complexes containing 4,4'-dipyridyldisulfide (4DPDS) ligands.
Reactions of half-sandwich iridium and rhodium complexes [Cp*MCl2]2 (1a: M = Ir, 1b: M = Rh) and the half-sandwich ruthenium complex [(p-cymene)RuCl2]2 (1c) with 4DPDS gave the correspondingExpand
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Stepwise formation of organometallic macrocycles, prisms and boxes from Ir, Rh and Ru-based half-sandwich units.
Over the past decade, supramolecular compounds with organometallic Ir, Rh, Ru based half-sandwich complexes have received considerable attention as materials with a variety of potential applications.Expand
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Half-sandwich iridium- and rhodium-based organometallic architectures: rational design, synthesis, characterization, and applications.
CONSPECTUS: Over the last two decades, researchers have focused on the design and synthesis of supramolecular coordination complexes, which contain discrete functional structures with particularExpand
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Formation of direct metal-metal bonds from 16-electron "pseudo-aromatic" half-sandwich complexes Cp''M[E2C2(B10H10)].
Continuous study on preparation of multimetallic clusters is stimulated by their rich coordination chemistry and promising applications in a variety of interesting fields. Although numerous effortsExpand
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Host-guest chemistry with bi- and tetra-nuclear macrocyclic metallasupramolecules.
Among the reported two-dimension macrocycles, bi- and tetra-nuclear macrocyclic metallasupramolecules are designed to have novel specific cavities with different shapes and dimensions, andExpand
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Postsynthetic modification of dicarbene-derived metallacycles via photochemical [2 + 2] cycloaddition.
Molecular squares obtained from two olefin-bridged bis(NHC) ligands, NHC-Ar-C═C-Ar-NHC, and two Ag(+) or Au(+) ions undergo postsynthetic modifications via a UV-irradiation-initiated [2 + 2]Expand
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