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Water-soluble CdSe and CdSe/CdS nanocrystals: a greener synthetic route.
Fine-tuning pore size by shifting coordination sites of ligands and surface polarization of metal-organic frameworks to sharply enhance the selectivity for CO2.
Based upon the (3,6)-connected metal-organic framework {Cu(L1)·2H(2)O·1.5DMF}(∞) (L1 = 5-(pyridin-4-yl)isophthalic acid) (SYSU, for Sun Yat-Sen University), iso-reticular {Cu(L2)·DMF}(∞) (L2 =
Finely tuning MOFs towards high performance in C2H2 storage: synthesis and properties of a new MOF-505 analogue with an inserted amide functional group.
Aiming to improve the acetylene (C2H2) storage capability of MOFs, NJU-Bai 17 is designed, a new analogue of MOF-505 with an inserted amide functional group which exhibits almost record high C 2H2 uptakes.
Ni-Catalyzed Reductive Cross-Coupling of Amides with Aryl Iodide Electrophiles via C-N Bond Activation.
This work is the first example using amide as an electrophile to couple with another electrophiles, instead of using highly basic and pyrophoric nucleophiles, and solves the problem that the Ni catalyst preferentially inserts the more reactive C-I bond to form a self-coupling product.
One-step solid-state thermolysis of a metal-organic framework: a simple and facile route to large-scale of multiwalled carbon nanotubes.
A simple and facile solid-state approach to large-scale synthesis of multiwalled carbon nanotubes (MCNTs) by one-step direct thermolysis of a metal-organic framework in a one-end closed conventional horizontal tube furnace under relatively low temperature without using any additional carrier gas or catalyst.
Ni-catalyzed deaminative cross-electrophile coupling of Katritzky salts with halides via C─N bond activation
This cross-coupling strategy of two electrophiles provides a highly valuable vista for the convenient installation of alkyl substituents and late functionalizations of sp3 carbons.
Access to Alkyl-Substituted Lactone via Photoredox-Catalyzed Alkylation/Lactonization of Unsaturated Carboxylic Acids.
An efficient photoredox-catalyzed alkylation/lactonization reaction of unsaturated carboxylic acids by using alkyl N-hydroxyphthalimide esters asAlkylation reagents has been developed, which provides a new strategy for the synthesis of alkyL substituted lactones.
Synthesis, Structure, Water-Induced Reversible Crystal-to-Amorphous Transformation, and Luminescence Properties of Novel Cationic Spacer-Filled 3D Transition Metal Supramolecular Frameworks from
Four novel cationic spacer-filled 3D transition metal supramolecular frameworks from N,N‘,N‘ ‘-tris(carboxymethyl)-1,3,5- benzenetricarboxamide (L), {[ML(H2O)3]2[M(H2O)6](H2O)3}n (M = Zn, 1; Mn, 2;