The Mn(III) ion in the title complex, [Mn(C(15)H(10)N(3)O)(2)]ClO(4)·H(2)O, is coordinated meridionally by six N atoms from two tridentate N-(8-quinol-yl)pyridine-2-carboxamidate ligands, yielding a distorted octa-hedral coordination geometry. The two ligands are nearly planar and their mean planes are almost perpendicular, with a dihedral angle of 86.7… (More)
In the title compound, [Mn(2)O(C(18)H(18)ClN(4))(2)](PF(6))(2), the Mn atom is chelated by a tetra-dentate ligand via four N atoms, and further bonded to one chloride ion and one bridging oxide, to give a centrosymmetric cation and distorted octa-hedral coordination geometry.
In the asymmetric unit of the title compound, [Mn(C(2)O(4))(C(3)H(10)N(2))(2)]Cl·H(2)O, there are two independent Mn(III) complexes, two Cl(-) anions and two uncoordinated water mol-ecules. Each Mn(III) atom is hexa-coordinated by four N atoms from two propane-1,3-diamine ligands and two O atoms from one oxalate ligand, resulting in a slightly distorted… (More)