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Resolution by high-performance liquid chromatography using polysaccharide carbamates and benzoates as chiral stationary phases
Polysaccharides such as cellulose and amylose are the most accessible optically active polymers and can be readily modified to triesters and triscarbamates. In this review, triscarbamates of the… Expand
Efficient Separation of Enantiomers Using Stereoregular Chiral Polymers.
Chromatographic resolution : XI. Controlled chiral recognition of cellulose triphenylcarbamate derivatives supported on silica gel
Abstract Cellulose triphenylcarbamate and eighteen mono- or disubstituted derivatives were adsorbed on silica gel and their chiral recognition abilities as stationary phases for high-performance… Expand
Polysaccharide Derivatives for Chromatographic Separation of Enantiomers.
Most racemates, from an analytical to a preparative scale, now appear to be resolved by this technique, and the chromatogram for the enantiomeric resolution of a fullerene derivative is shown. Expand
CHROMATOGRAPHIC RESOLUTION. 7. USEFUL CHIRAL PACKING MATERIALS FOR HIGH‐PERFORMANCE LIQUID CHROMATOGRAPHIC RESOLUTION OF ENANTIOMERS: PHENYLCARBAMATES OF POLYSACCHARIDES COATED ON SILICA GEL
Synthetic helical polymers: conformation and function.
Polysaccharide Derivatives for Chromatographic Separation of Enantiomers
Solvent-Induced Chiroptical Changes in Supramolecular Assemblies of an Optically Active, Regioregular Polythiophene
The solvent-induced chiroptical properties of an optically active, regioregular (head-to-tail) polythiophene bearing chiral oxazoline residues,… Expand
Chloromethylphenylcarbamate derivatives of cellulose as chiral stationary phases for high-performance liquid chromatography
A new class of eight chloromethylphenylcarbamate derivatives of cellulose was prepared by introducing both an electron-donating methyl group and an electron-withdrawing chloro group on to the phenyl… Expand
Polysaccharide derivatives as useful chiral stationary phases in high-performance liquid chromatography
The chromatographic separation of enantiomers using chiral stationary phases (CSPs) has significantly advanced. The esters and carbamates of polysaccharides coated on silica gel have been extensively… Expand