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ASYMMETRIC REDUCTION OF KETONES VIA HYDROSILYLATION CATALYZED BY A RHODIUM(I) COMPLEX WITH CHIRAL PHOSPHINE LIGANDS
Asymmetric reduction of ketones has been achieved via catalytic hydrosilylation using rhodium(I) complex with an optically active phosphine ligand as a catalyst.
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Polar Substituent Constants for Substituted Phenyl Groups. The Extended Taft Equation.
Values of the σ* constants have been defined for some m- and p-substituted phenyl groups from the 29Si–H coupling constants for a series of m- and p-substituted phenylsilanes, phenylmethylsilanes,Expand
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Structural specificity of synthetic peptide adjuvant for induction of experimental allergic encephalomyelitis.
Abstract The peptide N -acetylmuramyl- l -alanyl- d -isoglutamine (MDP), which has adjuvant activities, and 17 of its derivatives and analogs were synthesized and assayed to elucidate the structureExpand
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Rhodium complex catalysed hydrosilylation of carbonyl compounds
Chlorotris(triphenylphosphine)rhodium has been found to be an extremely effective catalyst for the hydrosilylation of carbonyl compounds.
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Air-Stable Tetrakis(2,4,6-triisopropylphenyl)disilene. Direct Synthesis of Disilene from Dihalomonosilane
The most air-stable disilene, tetrakis(2,4,6-triisopropylphenyl) disilene was obtained by the direct treatment of dichloromonosilane, bis(2,4,6-triisopropylphenyl)dichlorosilane, with lithiumExpand
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The first octasilacubane system: synthesis of octakis-(t-butyldimethylsilyl)pentacyclo[4.2.0.02,5.03,8.04,7]octasilane
The first octasilacubane, octakis-(t-butyldimethylsilyl)pentacyclo[4.2.0.02,5.03,8.04,7]octasilane, was synthesised in one step by condensation ofExpand
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