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ASYMMETRIC REDUCTION OF KETONES VIA HYDROSILYLATION CATALYZED BY A RHODIUM(I) COMPLEX WITH CHIRAL PHOSPHINE LIGANDS
Asymmetric reduction of ketones has been achieved via catalytic hydrosilylation using rhodium(I) complex with an optically active phosphine ligand as a catalyst.
Polar Substituent Constants for Substituted Phenyl Groups. The Extended Taft Equation.
Values of the σ* constants have been defined for some m- and p-substituted phenyl groups from the 29Si–H coupling constants for a series of m- and p-substituted phenylsilanes, phenylmethylsilanes,… Expand
Structural specificity of synthetic peptide adjuvant for induction of experimental allergic encephalomyelitis.
Abstract The peptide N -acetylmuramyl- l -alanyl- d -isoglutamine (MDP), which has adjuvant activities, and 17 of its derivatives and analogs were synthesized and assayed to elucidate the structure… Expand
Reduction of carbonyl compounds via hydrosilylation
Rhodium complex catalysed hydrosilylation of carbonyl compounds
Chlorotris(triphenylphosphine)rhodium has been found to be an extremely effective catalyst for the hydrosilylation of carbonyl compounds.
Reduction of Carbonyl Compounds with Various Hydrosilane-Rhodium(I) Complex Combinations
Air-Stable Tetrakis(2,4,6-triisopropylphenyl)disilene. Direct Synthesis of Disilene from Dihalomonosilane
The most air-stable disilene, tetrakis(2,4,6-triisopropylphenyl) disilene was obtained by the direct treatment of dichloromonosilane, bis(2,4,6-triisopropylphenyl)dichlorosilane, with lithium… Expand
Radical reactions in the coordination sphere I. Addition of carbon tetrachloride and chloroform to 1-olefins catalyzed by ruthenium(II) complexes.
The action of tris(triphenylphosphine)chlororhodium on polyhydromonosilanes
The first octasilacubane system: synthesis of octakis-(t-butyldimethylsilyl)pentacyclo[4.2.0.02,5.03,8.04,7]octasilane
The first octasilacubane, octakis-(t-butyldimethylsilyl)pentacyclo[4.2.0.02,5.03,8.04,7]octasilane, was synthesised in one step by condensation of… Expand