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Solid-state NMR of endohedral hydrogen-fullerene complexes.
We present an overview of solid-state NMR studies of endohedral H(2)-fullerene complexes, including (1)H and (13)C NMR spectra, (1)H and (13)C spin relaxation studies, and the results of (1)HExpand
Unsymmetrically substituted disilyne Dsi(2)(i)PrSi-Si≡Si-SiNpDsi(2) (Np = CH(2)(t)Bu): synthesis and characterization.
The unsymmetrically substituted disilyne, Dsi(2)(i)PrSi-Si≡Si-SiNpDsi(2) (Np = CH(2)(t)Bu) 2, was synthesized and characterized by X-ray crystallography to show a trans-bent structure with aExpand
Rotor in a cage: Infrared spectroscopy of an endohedral hydrogen-fullerene complex.
We report the observation of quantized translational and rotational motion of molecular hydrogen inside the cages of C(60). Narrow infrared absorption lines at the temperature of 6 K correspond toExpand
Cryogenic NMR spectroscopy of endohedral hydrogen-fullerene complexes.
We have observed 1H NMR spectra of hydrogen molecules trapped inside modified fullerene cages under cryogenic conditions. Experiments on static samples were performed at sample temperatures down toExpand
Quantum translator-rotator: inelastic neutron scattering of dihydrogen molecules trapped inside anisotropic fullerene cages.
We report an inelastic neutron scattering investigation of the quantum dynamics of hydrogen molecules trapped inside anisotropic fullerene cages. Transitions among the manifold of quantizedExpand
Quantum rotation and translation of hydrogen molecules encapsulated inside C60: temperature dependence of inelastic neutron scattering spectra
The quantum dynamics of a hydrogen molecule encapsulated inside the cage of a C60 fullerene molecule is investigated using inelastic neutron scattering (INS). The emphasis is on the temperatureExpand
High Pressure Effects on the Quantum Tunneling of Magnetization in Mn 12 Acetate
The effect of high pressure on the quantum tunneling of magnetization (QTM) in the single-molecule magnet, Mn 12 acetate (Mn 12 O 12 (O 2 CCH 3 ) 16 (H 2 O) 4 ), was studied at 2.4 K. As the pressureExpand
Inelastic neutron scattering of a quantum translator-rotator encapsulated in a closed fullerene cage : Isotope effects and translation-rotation coupling in H
A. J. Horsewill,1,* S. Rols,2 M. R. Johnson,2 Y. Murata,3 M. Murata,3 K. Komatsu,3 M. Carravetta,4 S. Mamone,4 M. H. Levitt,4 J. Y.-C. Chen,5 J. A. Johnson,5 X. Lei,5 and N. J. Turro5 1School ofExpand
29a-SA-12 Δ-Δ State in Deuteron
Infrared spectroscopy of an endohedral water in fullerene.
An infrared absorption spectroscopy study of the endohedral water molecule in a solid mixture of H2O@C60 and C60 was carried out at liquid helium temperature. From the evolution of the spectra duringExpand