Share This Author
Probing the mechanism of C-H activation: oxidation of methylcubane by soluble methane monooxygenase from Methylosinus trichosporium OB3b.
The reaction of methylcubane with the reconstituted MMO system from Methylosinus trichosporium OB3b yields both cubylmethanol andmethylcubanols, with methyl hydroxylation favored over cubyl hydroxYLation.
Mechanistic insights into C-H activation from radical clock chemistry: oxidation of substituted methylcyclopropanes catalyzed by soluble methane monooxygenase from Methylosinus trichosporium OB3b.
Tert-butylhydroperoxide bioactivation to methyl radical in rat liver mitochondria and submitochondrial particles.
- A. Iannone, A. Bini, Y. Jin, V. Vannini, A. Tomasi
- Chemistry, BiologyFree radical research communications
It is proposed that haem prosthetic groups are the likely source of TBH bioactivation in mitochondria by using EPR coupled to the spin trapping technique to detect carbon-centered radicals.
Excited States From Multi-Reference Coupled-cluster Theory to an Exact One-Particle DFT Theory
[Analysis of carbon number and ethylene oxide number distribution in alcohol ethoxylates by HPLC/electrospray ionization mass spectrometry].
The distribution of LION AEO3 (Dobanox25c), which has an alkyl chain with 12, 13, 14 and 15 carbon atoms, is determined using high performance liquid chromatography and on line electrospray mass spectrometry.