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Probing the mechanism of C-H activation: oxidation of methylcubane by soluble methane monooxygenase from Methylosinus trichosporium OB3b.
TLDR
The reaction of methylcubane with the reconstituted MMO system from Methylosinus trichosporium OB3b yields both cubylmethanol andmethylcubanols, with methyl hydroxylation favored over cubyl hydroxYLation.
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Mechanistic insights into C-H activation from radical clock chemistry: oxidation of substituted methylcyclopropanes catalyzed by soluble methane monooxygenase from Methylosinus trichosporium OB3b.
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Tert-butylhydroperoxide bioactivation to methyl radical in rat liver mitochondria and submitochondrial particles.
TLDR
It is proposed that haem prosthetic groups are the likely source of TBH bioactivation in mitochondria by using EPR coupled to the spin trapping technique to detect carbon-centered radicals.
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Excited States From Multi-Reference Coupled-cluster Theory to an Exact One-Particle DFT Theory
[Analysis of carbon number and ethylene oxide number distribution in alcohol ethoxylates by HPLC/electrospray ionization mass spectrometry].
  • X. Wang, Y. Jin
  • Chemistry
    Se pu = Chinese journal of chromatography
  • 1 July 2000
TLDR
The distribution of LION AEO3 (Dobanox25c), which has an alkyl chain with 12, 13, 14 and 15 carbon atoms, is determined using high performance liquid chromatography and on line electrospray mass spectrometry.
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The interaction of excited coherent states and their superpositions with two-level atoms
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