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Based on a metal-templated approach using a rigid and globular structural scaffold in the form of a bis-cyclometalated octahedral iridium complex, an exceptionally active hydrogen-bond-mediated… Continue Reading
A copper-catalyzed B-H bond insertion reaction with amine- and phosphine-borane adducts was realized with high yield and enantioselectivity under mild reaction conditions. The B-H bond insertion… Continue Reading
Reactions of the binary Zintl anion (Pb2Bi2)2- with Ln(Me4Cp)3 (Ln: La, Ce, Nd, Gd, Sm, Tb) in presence of [2.2.2]crypt in en/toluene yields ten [K([2.2.2]crypt)]+ salts of Ln-doped semimetal… Continue Reading
The N-heterocyclic carbene-catalyzed conjugate Umpolung of differently substituted α,β-unsaturated aldehydes, e. g. cinnamaldehydes, a-methylcinnamaldehydes, and crotonaldehydes, is described.… Continue Reading
The synthetic use of pseudo-homoatomic Pb-—Bi Zintl anions as an efficient approach to the first M@Pb—Bi ternary intermetalloid clusters with reasonable yields is demonstrated.
Syntheses of [K([2.2.2]crypt)](+) salts of binary Pb-Bi Zintl anions and their reaction with ZnPh(2) or Ni(cod)(2), yielding ternary intermetalloid Ni-Pb-Bi or Zn-Pb-Bi clusters, proved the use of… Continue Reading