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Here, we show a CuBr2-catalyzed approach for a highly enantioselective synthesis (93-99% ee) of allenols from aldehydes and terminal alkynols with the absolute configuration being controlled by applying readily available (R)- or (S)-α,α-diphenylprolinol.
Gold hollow superparticles are prepared taking advantage of the dopamine chemistry. The plasmon coupling of the gold nanoparticles makes the superparticles an effective photothermal conversion agent in the photothermal therapy of cancer. Moreover, the mussel-inspired assembly approach could be extremely useful for the transfer of nanomaterial science to… (More)
Oxidation from alcohols to carboxylic acids, a class of essential chemicals in daily life, academic laboratories, and industry, is a fundamental reaction, usually using at least a stoichiometric amount of an expensive and toxic oxidant. Here, an efficient and practical sustainable oxidation technology of alcohols to carboxylic acids using pure O2 or even O2… (More)