Xin-rong Zhang

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In the rapid development of nanoscience and nanotechnology, many researchers have discovered that metal oxide nanoparticles have very useful pharmacological effects. Cuprous oxide nanoparticles (CONPs) can selectively induce apoptosis and suppress the proliferation of tumor cells, showing great potential as a clinical cancer therapy. Treatment with CONPs(More)
The structures of two mononuclear transition-metal complexes with tri-cyano-methanide (tcm(-)) and 1,4,7,10-tetra-aza-cyclo-dodecane (cyclen) ligands, [Ni(C4N3)2(C8H20N4)], (I), and [Cu(C4N3)(C8H20N4)](C4N3), (II), are reported. In the neutral complex (I), the nickel cation is coordinated by one cyclen ligand and two monodentate N-bound tcm(-) anions in a(More)
In the title complex, [Ni(C2N3)2(C9H24N4)], the Ni(II) atom is coordinated in a distorted octa-hedral geometry by one tris-(3-amino-prop-yl)amine (tris-apa) ligand and two dicyanamide (dca) ligands [one of them disordered in a 0.681 (19):0319 (19) ratio]. Inter-molecular N-H⋯N hydrogen bonds involving the N atoms of the dca anions and the tris-apa amine H(More)
In the title compound, [Co(C(4)N(3))(2)(C(10)H(8)N(2)O(2))]·2H(2)O, a novel tricyano-methanide complex, the Co(II) atom is located on an inversion center and has a distorted octa-hedral coordination with two 2,2'-bipyridyl dioxide (dpdo) mol-ecules and two trans tricyano-methanide (tcm) anions. The equatorial plane is formed by the four O atoms of the two(More)
The title complex, [Co(C(15)H(11)N(3))(2)](C(4)N(3))(2), is built up from discrete [Co(terpy)(2)](2+) cations (terpy is 2,2':6',2''-terpyridine) and [C(CN)(3)](-) anions. In the cation, the Co(II) atom is coordinated by two terpy mol-ecules, giving a distorted octa-hedral geometry. The tricyano-methanide anions are not directly coordinated to the Co(II)(More)
In the title complex, [Ni(C(4)N(3))(2)(C(15)H(11)N(3))](n), each of the two different Ni(II) atoms is coordinated by one 2,2':6'2''-terpyridine (terpy) and three tricyano-methanide ligands in a distorted octa-hedral geometry. The Ni(II) atoms are linked to each other, forming an infinite chain parallel to (10). π-π Stacking inter-actions of terpy mol-ecules(More)
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