Xin Gan

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In the title mononuclear Cu(I) complex, [Cu(C(18)H(15)P)(C(41)H(39)P(3))]BF(4), the cation has a basic rigid core structure reminiscent of the framework of diamond. The metal atom is coordinated by four P atoms in a distorted tetra-hedral geometry, the distortion arising from the steric hindrance of the phenyl groups. The anion is disordered over two(More)
The title dinuclear copper(I) complex, {[Cu(2)(C(2)H(3)N)(C(12)H(10)N(2))(C(25)H(22)P(2))(2)](BF(4))(2)}(n), contains 1,2-di-4-pyridyl-ethene, bis-(diphenyl-phosphino)methane and acetonitrile ligands. The two Cu atoms, one with an N(2)P(2) ligand set and the other with an NP(2) ligand set, are bridged by two bis-(diphenyl-phosphino)methane ligands, forming(More)
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