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Oxidative Synthesis of Quinazolinones under Metal‐free Conditions
A metal-free procedure for the synthesis of quinazolinones under oxidative conditions has been developed. In the presence of DABCO and TBHP, the desired products can be obtained in moderate yieldsExpand
Selective Preparation of Xanthones from 2-Bromofluorobenzenes and Salicylaldehydes via Palladium-Catalyzed Acylation–SNAr Approach
A regioselective pathway for the preparation of xanthones from 2-bromofluorobenzenes and salicylaldehydes has been developed. The reaction proceeded through palladium-catalyzed acylation–S N ArExpand
Palladium-catalyzed carbonylative coupling of aryl iodides with an organocopper reagent: a straightforward procedure for the synthesis of aryl trifluoromethyl ketones
A palladium-catalyzed carbonylative coupling of aryl iodides with a (trifluoromethyl)copper reagent has been developed. A wide range of substrates have been transformed into their correspondingExpand
Palladium-catalyzed carbonylative coupling reactions between Ar-X and carbon nucleophiles.
A critical review of the development of palladium-catalyzed carbonylative coupling reactions of aromatic halides and related compounds with carbon nucleophiles with palladium catalysts concludes that these reactions are important intermediates in the manufacture of dyes, pharmaceuticals, agrochemicals, and other industrial products. Expand
From noble metal to Nobel Prize: palladium-catalyzed coupling reactions as key methods in organic synthesis.
The coupling protocol for aryl halides with olefins can be considered as a milestone for the development and application of organometallic catalysis in organic synthesis and set the stage for numerous further applications. Expand
Transition-metal-catalyzed carbonylation reactions of olefins and alkynes: a personal account.
This Account discusses the work on various carbonylations of unsaturated compounds and related reactions, and develops so-called alternative metal catalysts based on iridium, ruthenium, and iron for carbonylation reactions with carbon monoxide. Expand
The Applications of Dimethyl Sulfoxide as Reagent in Organic Synthesis
Dimethyl sulfoxide (DMSO) is one of the most commonly applied organic solvents in chemical transformations and is utilized widely in industrial processes as well. During the past decades, numerousExpand